State-owned China Development Bank, which does the bidding of Beijing, and Barclays PLC will team up in a wide-ranging deal under which the British lender will offer services to the Chinese bank around the world.

Stock and bond sales, foreign-exchange trading, day-to-day commercial banking and staff training are among the areas covered by the agreement--as is helping CDB buy overseas assets. Barclays is strong in Europe, the U.S. and most significantly in Africa, where Chinese state-backed companies have been ramping up as part of government-backed push to secure resources, particularly energy and minerals.

"We will show them ideas, targets and also financing structures so that CDB will be able to buy the target," said Philip Tsao, managing director and head of global finance and risk solutions for Greater China at Barclays. "It is for Barclays and CDB a pretty significant step forward."

CDB began more than two decades ago as one of three "policy lenders' that provided funds to state companies whose actions were aligned with government policy. With Barclays as a partner, CDB's overseas reach comes full circle. Its first international move away from lending to state-owned firms came with its 2007 acquisition of a 3.1% stake in Barclays, to finance the U.K. bank's ultimately unsuccessful bid for ABN Amro Holding. That stake has been diluted over the years and is now just over 1%.

The new agreement, known as a memorandum of understanding, replaces pacts the two have signed since 2007.

At one time, CDB did most of its business inside China and occasionally financed natural-resources deals for Chinese companies, but it made a big splash when it lent money to e-commerce company Alibaba Group and to fund the Hong Kong Exchanges & Clearing Ltd.'s purchase of the London Metal Exchange in 2012.

It recently pulled back from those types of deals.

Africa could be a key element of the pairing's strategy. CDB has been a major lender to Chinese firms setting up mines and building infrastructure projects across the continent, and it runs a private-equity fund aimed at supporting local small and midsize businesses there. Barclays Africa is one of the continent's largest financial institutions, with operations in South Africa, Botswana, Ghana, Kenya, Mauritius, Seychelles, Tanzania, Uganda and Zambia and plans to further develop the business.

"We have hired Mandarin speakers in Africa to serve our clients from China, including CDB," Mr. Tsao said. "We will offer a lot of training to their staff in Africa."

It is a road pioneered by Industrial & Commercial Bank of China Ltd. and South African lender Standard Bank Group Ltd., Africa's largest homegrown bank by assets. In 2007 ICBC paid $5.5 billion for a 20% stake in the South African lender, a deal seen at the time as a way to open up Africa to the Chinese bank. ICBC later bought 80% of Standard Bank's operations in Argentina for $600 million, and earlier this year added 60% of Standard Bank's commodities- and foreign- exchange-trading business in London for an estimated $765 million.

CDB hasn't demonstrated the kind of international ambition that has led ICBC to buy banks in North America, Thailand and Indonesia and set up dozens of branches globally. CDB has a limited permanent presence overseas, with offices in Cairo and Moscow, according to the bank's website.

CDB has signed agreements such as MOUs before, sometimes with little significant outcome. In recent years Nomura Holdings signed a pact with CDB Securities, while CDB International Holdings signed agreements with private-equity firm Kohlberg Kravis Roberts and TPG Inc. to pursue co-investing opportunities.

At the end of 2012, Barclays Africa--then known as Absa Group--moved to bolster its China business when it hired as its chief executive of retail and business banking the man in charge of Standard Bank's China operations in Beijing, Craig Bond. Mr. Bond had been in charge of shepherding the South African bank's relationship with ICBC.

Standard Bank and CDB have long had a close relationship. In 2012 Standard Bank acted as the sole bookrunner of CDB's 500 million yuan ($80.6 million) sale of bonds to African central banks, and the Chinese bank has also provided financing for Standard Bank's lending program for small businesses in South Africa. The two banks also occupy the same office building in Beijing--across the road from ICBC. But ICBC's partnership constrains CDB's scope to cooperate with Standard Bank on deals.

As of the end of 2013, CDB's total foreign-currency loans had reached $292 billion and its total assets were valued at more than eight trillion yuan ($1.3 trillion), according to its website.

Write to Enda Curran at enda.curran@wsj.com and Dinny McMahon at dinny.mcmahon@wsj.com

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